Posted by - qian liu -
on - November 23, 2023 -
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Ultrasonic Oxidative Desulfurization
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Sulfur is a naturally occurring element that is found in crude oil. When crude oil is burned, the sulfur in the oil is converted to sulfur dioxide (SO2), which is a harmful air pollutant. SO2 can cause respiratory problems, acid rain, and other environmental damage.
To reduce the amount of SO2 emissions from burning crude oil, refineries must remove sulfur from the oil before it is burned. There are a number of different methods for removing sulfur from crude oil, including hydrodesulfurization (HDS) and oxidative desulfurization (ODS).
HDS is the most common method for removing sulfur from crude oil. However, HDS is a high-energy and capital-intensive process. ODS is a more environmentally friendly and cost-effective alternative to HDS.
What is Ultrasonic Oxidative Desulfurization (UAOD)?
Ultrasonic oxidative desulfurization (UAOD) is an emerging ODS technology that utilizes the action mechanism of ultrasonic waves to form a fine emulsion, enhance the mixing intensity between two immiscible phases, and increase the rate of the ODS reaction.
UAOD is a two-stage process that involves the following steps:
Oxidation: The sulfur in the crude oil is oxidized to sulfates using an oxidizing agent, such as hydrogen peroxide.
Extraction: The sulfates are removed from the crude oil using a solvent, such as water.
Advantages of UAOD
UAOD has several advantages over other ODS methods, including:
Low energy consumption: UAOD is a low-energy process that requires less energy than HDS.
Low capital cost: UAOD is a relatively low-cost process compared to HDS.
High desulfurization efficiency: UAOD can remove up to 99% of the sulfur from crude oil.
Environmentally friendly: UAOD does not produce any harmful byproducts.
Applications of UAOD
UAOD is being used to desulfurize a variety of fuels, including:
Diesel fuel: UAOD is being used to produce ultra-low sulfur diesel (ULSD).
Gasoline: UAOD is being used to produce low-sulfur gasoline (LSG).
Marine fuel: UAOD is being used to produce marine fuel oil (MFO) with a sulfur content of 0.5% or less.
Conclusion
UAOD is a promising ODS technology that has the potential to revolutionize the way we desulfurize fuels. UAOD is a low-energy, low-cost, and environmentally friendly process that can remove up to 99% of the sulfur from crude oil. UAOD is being used to produce ULSD, LSG, and MFO. As the demand for cleaner fuels continues to grow, UAOD is likely to play an increasingly important role in the refining industry.
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